Cards can come and go but CW01 will always be the first card (collector numberwise at least)
About which packs to buy, actually it does not matter that much since the probability of getting what you want is low, but, to maximize it, Id recommend getting Amonkhet for Hazoret the Fervent, Glorybringer, Ahn-Crop Crasher, Magma Spray and Sunscorched Desert
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Guided by Nature The green preconstructed deck was forgettable, but the two legendary permanents that came out of this deck are some of the most popular mono-green utility cards that have seen print: Freyalise and Titania
In cube this is painfully slow and frequently a liability